Porous manganese carbonate was obtained via solvothermal synthesis using ethanol and urea. The manganese carbonate was subsequently used as a precursor to synthesise mesoporous manganese oxides via thermal treatments at three various temperatures. X-ray diffraction and Extended X-ray Absorption Fine Structure (EXAFS) results shows that γ-MnO₂ is synthesised at 380 and 450 °C while Mn₂O₃ is produced at the annealing temperature of 575 °C. X-ray absorption spectra show that γ-MnO₂ converts completely to Mn₂O₃ after annealing over the 450–575 °C range. The oxides obtained at 380 °C and 450 °C possess extremely high specific surface area, which is of interest for catalytic applications. The oxides were investigated as electrocatalysts for the oxygen evolution reaction; the oxide prepared at the lowest annealing temperature was found to be the optimum catalyst with an overpotential of 427 ± …