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Autoren:
Synnatschke, Kevin; Jonak, Martin; Storm, Alexander; Laha, Sourav; Köster, Janis; Petry, Julian; Ott, Steffen; Szydłowska, Beata; Duesberg, Georg S.; Kaiser, Ute; Klingeler, Rüdiger; Lotsch, Bettina V.; Backes, Claudia 
Dokumenttyp:
Zeitschriftenartikel / Journal Article 
Titel:
Sonication-assisted liquid exfoliation and size-dependent properties of magnetic two-dimensional α-RuCl3 
Zeitschrift:
Journal of Physics D: Applied Physics 
Jahrgang:
56 
Heftnummer:
27 
Jahr:
2023 
Seiten von - bis:
274001 
Sprache:
Englisch 
Stichwörter:
liquid phase exfoliation ; RuCl3 ; 2D material ; size selection ; nanomaterial stability 
Abstract:
Originating from the hexagonal arrangement of magnetic ions in the presence of strong spin orbit coupling, α-RuCl3 is considered as model system for the Kitaev-Heisenberg model. While the magnetic properties of α-RuCl3 have been studied in bulk single crystals or micromechanically-exfoliated nanosheets, little is known about the nanosheets’ properties after exfoliation by techniques suitable for mass production such as liquid phase exfoliation (LPE). Here, we demonstrate sonication-assisted LPE on α-RuCl3 single crystals in an inert atmosphere. Coupled with centrifugation-based size selection techniques, the accessible sizeand thickness range is quantified by statistical atomic force microscopy. Individual nanosheets obtained after centrifugation-based size selection are subjected to transmission electron microscopy to confirm their structural integrity after the exfoliation. The results are combined with bulk characterisation methods, including Raman and x-ray photoelectron spectroscopy, and powder diffraction experiments to evaluate the structural integrity of the nanosheets. We report changes of the magnetic properties of the nanomaterial with nanosheet size, as well as photospectroscopic metrics for the material concentration and average layer number. 
ISSN:
1361-6463 
Article-ID:
274001 
Fakultät:
Fakultät für Elektrotechnik und Informationstechnik 
Institut:
EIT 2 - Institut für Physik 
Professur:
Düsberg, Georg 
Projekt:
Graphene Flagship Core 3; Vital Sense 
Open Access ja oder nein?:
Ja / Yes 
Art der OA-Lizenz:
CC BY 4.0